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Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. The coal tar pitch compound must be in a solid mass during transportation. The provisions of this special provision will be effective until January 2, 2023, unless we terminate them earlier or extend them beyond that date by notice of a final rule in the Federal Register. W7 Vessel stowage category for uranyl nitrate hexahydrate solution is D as defined in 172.101(k)(4). See Batteries, dry, sealed, n.o.s. in the 172.101 Hazardous Materials Table (HMT) of this part for transportation requirements for nickel-metal hydride batteries transported by other modes and for nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel. b. TP12 This material is considered highly corrosive to steel. Transport in accordance with this special provision must be noted on the shipping paper. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. be marked with the hydrostatic pressure test marking specified in 173.24a(b)(4). The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. If a fuel cell engine is installed in a vehicle, the vehicle must be described using Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the 172.101 Table. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. (5) N codes. TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 C (90.5 F). the hierarchy of the document. B67 All valves and fittings must be protected by a securely attached cover made of metal not subject to deterioration by the lading, and all valve openings, except safety valve, must be fitted with screw plugs or caps to prevent leakage in the event of valve failure. In addition, the material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. This contact form is only for website help or website suggestions. 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. Additionally, unless otherwise excepted in this subchapter, polyester resin kits must be packaged in specification combination packagings based on the performance level of the base material contained within the kit. Radiation detection systems containing such detectors are not subject to any other requirements of this subchapter provided they are packed in accordance with paragraph c of this special provision. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. When such batteries are transported in accordance with 173.185(c), the total lithium content of all lithium metal cells contained in the battery must not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery must not exceed 10 Wh. Table 1 authorizes IBCs for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. c. The motor carrier must maintain a satisfactory safety rating as prescribed in 49 CFR part 385. 107 The classification of the substance is expected to vary especially with the particle size and packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in 173.57 and 173.58 of this subchapter. Table 2 defines IP Codes on the use of IBCs that are assigned to specific commodities in the 172.101 Table of this subchapter. j. For criteria in determining what is a new lighter design, see 173.308(b)(1). Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). d. The proper shipping name Printing ink related material may be used for consignments of packages containing Printing ink and Printing ink related material in the same package. 1/1.1 This content is from the eCFR and is authoritative but unofficial. A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. (i) Column 8: Packaging authorizations. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices containing Class 1 (explosive) materials or materials of other hazard classes. 160 This entry applies to safety devices for vehicles, vessels or aircraft, e.g. In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. 49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Column 1 specifies the T Code. Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. B82 Cargo tanks and portable tanks are not authorized. (ii) One bottle for every two hours of production, or for every 2,500 bottles produced, must be tested by dropping a bottle filled to 98 percent capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. This includes vehicles transported in a packaging. However this examination is required when the conditions of 180.605(f) are met. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of this subchapter. A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. For transportation by aircraft, a telephone report in accordance with 171.15(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a dry battery. 13 The words Inhalation Hazard shall be entered on each shipping paper in association with the shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. This web site is designed for the current versions of 420 This entry does not apply to manufactured articles (such as table tennis balls). N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 66 Formulations of these substances containing not less than 30 percent non-volatile, non-flammable phlegmatizer are not subject to this subchapter. This entry also applies to articles not conforming to the requirements of 173.302, 173.304, or 173.306 of this subchapter, containing a small pressure receptacle with a release device. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). and are not subject to requirements of this subchapter except for the following: (a) Incident reporting. 162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the shipping description. 170 Air must be eliminated from the vapor space by nitrogen or other means. A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. 121 This substance, when containing less alcohol, water or phlegmatizer than specified, may not be transported unless approved by the Associate Administrator. Packagings may include a vent to permit the slow escape of gas (i.e. This is an automated process for 181 When a package contains a combination of lithium batteries contained in equipment and lithium batteries packed with equipment, the following requirements apply: a. (3) Damage to terminals. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. 172 This entry includes alcohol mixtures containing up to 5% petroleum products. 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Explosives shipped in conformance with this paragraph must have been examined in accordance with 173.56 of this subchapter and approved by the Associate Administrator. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs: B1 If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. It may not be used to describe articles, machinery, or apparatus for which a proper shipping name exists in the 172.101 Table. 140 This material is regulated only when it meets the defining criteria for a hazardous substance or a marine pollutant. The shipper must ensure that all applicable requirements of 173.185 of this subchapter are met. A current copy of CGA pamphlet, CGA C-6 must be available at the facility servicing the life-saving appliance. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by 180.605 of this subchapter must be conducted. N5 Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the hazardous material. The material must be loaded dry. The map below, compiled from data provided by the Federal Emergency Management Agency (FEMA), is the most accurate nuclear attack map and fallout demonstration available for 2023: (Image courtesy of FEMA and Halcyon Maps) The fallout would rapidly spread, turning targeted cities into whole affected regions. Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig). 39 This substance may be carried under provisions other than those of Class 1 only if it is so packed that the percentage of water will not fall below that stated at any time during transport. 172-123, 55 FR 52582, Dec. 21, 1990]. Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. result, it may not include the most recent changes applied to the CFR. The adsorption or absorption presents the following properties: (1) The pressure at a temperature of 20 C (68 F) in the receptacle is less than 0.6 bar (60 kPa); (2) The pressure at a temperature of 35 C (95 F) in the receptacle is less than 1 bar (100 kPa); (3) The pressure at a temperature of 85 C (185 F) in the receptacle is less than 12 bar (1200 kPa). 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. a. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. The official, published CFR, is updated annually and available below under b. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. After filling, each glass inner packaging must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 C is achieved. Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). b. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. (1) Numeric provisions. A210 This substance is forbidden for transport by air. In this case, some parts of the vehicle may be detached from its frame to fit into the packaging. W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. Except as provided in 173.185(c)(3) of this subchapter, the package must be marked UN 3091 Lithium metal batteries packed with equipment, or UN 3481 Lithium ion batteries packed with equipment, as appropriate. f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. (3) B codes. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code or codes, there may be several of them is in addition to the generalpackaging requirements of173.24and any other applicable packaging requirements in Part 173. 109 Rocket motors must be nonpropulsive in transportation unless approved in accordance with 173.56 of this subchapter. When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. 381 For railroad flagging kits, see 173.184 (c) of this subchapter. 142 These hazardous materials may not be classified and transported unless authorized by the Associate Administrator. 336 The use of UN1H1 drums, UN3H1 jerricans, and UN6HA1 composite packagings which meet the requirements of part 178 of the HMR at the Packing Group I or II performance level. 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. B133 Hydrochloric acid concentration not exceeding 38%, in Packing Group II, is authorized to be packaged in UN31H1 or UN31HH1 intermediate bulk containers when loaded in accordance with the requirements of 173.35(h) of this subchapter. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. In addition, a lighter design intended to contain a non-pressurized Class 3 material is excepted from the examination and testing criteria specified in 173.308(b)(3). When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. Data collection and handling. Column 4 specifies the applicability of 178.275(g)(3) of this subchapter for the pressure relief devices. The proper shipping name Paint related material may be used for consignments of packages containing Paint and Paint related material in the same package; b. For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. b. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). Batteries must be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short circuits. After unloading, the residual material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water. 144 If transported as a residue in an underground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see 171.7 of this subchapter), then the tank and this material are not subject to any other requirements of this subchapter. B135 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be hermetically sealed. in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. Further, the limitations and/or additional requirements found in the special provisions of column 7 will supersede the packaging authorizations of column 8 of the Hazardous Materials Table. N36 Aluminum or aluminum alloy construction materials are permitted only for halogenated hydrocarbons that will not react with aluminum. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. Each tank must be equipped with pressure relief devices conforming to the following requirements: 1 Total venting capacity in standard cubic feet hour (S.C.F.H.) full text search results 430 This entry shall only be used for solid medical waste of Category A transported for disposal. 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. Prohibited means bottom openings are prohibited, and Prohibited for liquids means bottom openings are authorized for solid material only. Testing must be conducted on at least three packages as prepared for transport. TP18 The temperature of this material must be maintained between 18 C (64.4 F) and 40 C (104 F) while in transportation. Shipping papers at all times must reflect a correct current accounting of all cylinders both full and expended. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). c. Packagings are excepted from the design stress limits at elevated temperatures, as described in Section VIII of the ASME Code (IBR, see 171.7 of this subchapter). Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (1) A flammable liquid is a liquid having a flashpoint of not more than 93 C (200 F); (2) A flammable solid is a solid that meets the criteria in 173.124 of this subchapter; or. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. 15 This entry applies to Chemical kits and First aid kits containing one or more compatible items of hazardous materials in boxes, cases, etc. A13 Bulk packagings are not authorized for transportation by aircraft. 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. 3 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone C (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 337 Authorizes the use of regulated waste containers manufactured prior to October 1, 2006 to be marked with the alternative shipping name of Regulated medical waste, UN3291 and arrows that deviate as prescribed in 172.312(a)(2) in that they may be black or white. These special provisions are in addition to the standard packaging requirements. 196 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 C (115 F). A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. Note that batteries utilizing different chemistries (i.e., those battery chemistries specifically covered by another entry in the 172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent batteries in the same package. A60 Sterilization devices, when containing less than 30 mL per inner packaging with not more than 150 mL per outer packaging, may be transported in accordance with the provisions in 173.4a, irrespective of 173.4a(b), provided such packagings were first subjected to comparative fire testing. B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. 106 The recognized name of the particular explosive may be specified in addition to the type. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. W31 Non-bulk packagings must be hermetically sealed. b. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division.